ABRAHAM BALDWIN AGRICULTURAL COLLEGE

 

DIVISION OF SCIENCE & MATHEMATICS

 

SPRING SEMESTER 2008

 

CRN: 30231

 

SYLLABUS

Instructor: Dr. Barry Miburo

Office: Gray Hall, Room S-216

Phone: 391-5117

E-mail: bmiburo@abac.edu

 

INSTRUCTOR’S Work  Schedule:

Details about my work schedule may be found on this link: http://www.abac.edu/bmiburo/Sp08Schedule.htm

 

 

Course Syllabus

 

Course Name: 

 

FUNDAMENTAL ORGANIC CHEMISTRY II

 

Course Number:

 

CHEM 2041

 

Course Description:

 

This course is a continuation of CHEM 2040. Selected topics include aromatic compounds, ketones and aldehydes, carboxylic acids, amines, and amides. The structure, function, and reactivity of these compounds are investigated. IR, MS, and NMR spectroscopies are utilized as an aid in determining the structure of simple organic compounds. Spring.  3 credit hours.

 

Pre-requisites/Co-requisites:

 

Prerequisite:  CHEM 2040 and 2040L with a grade of C or better.

Co-requisite: CHEM 2041L.

 

USG General Education Outcomes pertinent to this course:

 

Scientific Reasoning: Scientific reasoning will be characterized by understanding and applying scientific method, laboratory techniques, mathematical principles, and experimental design to natural phenomena.

 

Competence within the context of collegiate general education objectives is defined by the following outcomes:

 

o        Ability to understand basic scientific principles, theories, laws as they apply to all scientific disciplines;

o        Ability to demonstrate knowledge in at least one area of science;

o        Ability to discern the role in and impact on science on society;

o        Ability to identify and properly use appropriate technologies for scientific inquiry and communication including collecting and analyzing scientific data;

o        Ability to understand the physical universe and science's relationship to it;

o        Ability to understand the changing nature of science;

o        Ability to understand the scope and limits on the appropriateness of scientific inquiry to physical phenomena;

o        Ability to demonstrate critical observation and analysis;

  • Ability to apply mathematical principles to scientific inquiry, including the use of statistics and formulae to understand quantitative data.

 

 

 

ABAC Course Learning Outcomes:

 

Fundamental Organic Chemistry II Course Outcomes:

 

1        Describe and explain the basic principles and the operation of mass spectrometry (MS) and infrared spectroscopy (IR)

2        Use MS and IR spectra to identify the structure of structural characteristics of organic compounds

3        Describe and explain the basic principles and the operation of nuclear magnetic resonance (NMR) spectroscopy

4        Use NMR spectra to identify the structure or structural characteristics of organic compounds

5        Describe and explain the mechanism, kinetics and stereochemistry and predict the outcome and the influential factors of elimination reactions

6        Describe and explain the mechanism and predict the outcome and the influential factors of electrophilic aromatic substitution reactions

7        Determine the names of aldehydes and ketones based on their structures

8        Determine the structures of aldehydes and ketones based on their names

9        Describe and explain properties, preparation methods and reactions of aldehydes and ketones

10    Determine the names of carboxylic acids and based on their structures

11    Determine the structures of carboxylic acids and based on their names

12    Describe and explain properties, preparation methods and reactions of carboxylic acids

13    Determine the names of carboxylic acid derivatives based on their structure

14    Determine the structures of carboxylic acid derivatives based on their names

15    Describe and explain properties, preparation methods and reactions of carboxylic acid derivatives

16    Describe and explain the mechanism and predict the outcome and the influential factors of alpha substitution and condensation reactions of enols and enolates

17    Determine the names of amines based on their structures

18    Determine the structures of amines based on their names

19    Describe and explain properties, preparation methods and reactions of amines

 

College Policy on Class Attendance:

 

ATTENDANCE

      Courses at Abraham Baldwin Agricultural College are provided for the intellectual growth and development of students.  To attain maximum success, students must attend all their classes, be on time, and attend all scheduled course activities including, but not limited to, field trips, seminars, study sessions, individual conferences, and lectures.  This interaction with instructors and other students is an important element of the learning process, and a high correlation exists between class attendance and course grades. A student must understand the importance of regular participation in classroom and laboratory activities. The absence of any student affects not only his or her performance but also the performance of the class as a whole. Absence from class, for whatever reason, does not excuse a student from full responsibility for class work or assignments missed. Students must accept this responsibility. 

      Instructors will keep accurate attendance records and must report the individual number of absences with midterm and final grades. Students whose number of unexcused absences is more than twice the number of class meetings per week (the equivalent of two weeks of instruction) will receive a grade of “F” for the course.  Fewer absences than twice the number of class meetings per week may result in grade penalties at the discretion of the instructor.  Specific attendance requirements applying to labs, clinics, accelerated classes or Learning Support will be adapted to the unique situation by the appropriate division.  Final determination of what constitutes an excused absence rests with the classroom instructor.  In implementing this Policy, faculty will not include in a student’s unexcused absences those absences incurred due to authorized and approved College sponsored events (or in the case of joint-enrollment students high-school sponsored events) in which the student represents the institution as part of a group or under the direct supervision of a faculty or staff member.

Whenever a student is absent, whether for official or personal reasons, the student must assume responsibility and provide notice to the instructor, preferably in advance, for making arrangements for any assignments and class work missed because of the absence. However, final approval for make up work remains with the individual instructor. 

     A student who stops attending class without officially withdrawing from the course is subject to this attendance policy and will receive a grade of “F” for the course. 

     At the beginning of each semester, instructors will explain clearly to their students’ specific attendance requirements (including possible penalties). Additionally, they will publish the attendance policy on their syllabi and web sites.

     A student penalized for excessive absences may appeal through the grade appeal

process, as stated in ABAC’s college catalog and student handbook.

 

 

 

INSTITUTIONAL ABSENCE

     A student who serves as an official representative of the college is defined as one who:

 

     is authorized to use the college name in public relationships outside the institution;

     regularly interacts with non-college individuals and groups over an extended period of time

            (at least one semester);

      represents the college as a part of a group and not as an individual;

      represents the college under the direct supervision of a college faculty or staff member; and

      is authorized in writing, in advance, by the President of the college.

 

      Such a student is in no way released from the obligations and responsibilities of all students, but will not be penalized with unexcused absences when absences result from regularly scheduled activities in which he/she represents the college.

      Further, it is the responsibility of each student to contact instructors prior to the absence and to make arrangements to make up any work that will be missed, in a manner acceptable to the instructor. Advisors of activities will schedule off-campus activities in a manner that does not unduly disrupt the learning process for a student.

 

http://www.abac.edu/catalog/2007_2008/AcademicPolicy.pdf

 

 

College Policy on Academic Dishonesty:

 

ACADEMIC DISHONESTY

     Because Abraham Baldwin Agricultural College has the dual responsibility of educating students and helping them mature into worthy citizens who take their place in the larger community, it has adopted a code for dealing with academic irregularities.

     Academic irregularities include, but are not limited to, giving or receiving of unauthorized assistance in the preparation of any academic or clinical assignment; taking or attempting to take, stealing, or otherwise obtaining in an unauthorized manner any material pertaining to the education process; selling, giving, lending, or otherwise furnishing to any person any question and/or answers to any examination known to be scheduled at any subsequent date; fabricating, forging, or falsifying lab or clinical results; plagiarism in any form related to themes, essays, term papers, tests, and other assignments; breaching any confidentiality regarding patient information.

 

Due Process for Academic Dishonesty Cases

 

Step 1. When a faculty member suspects that a student has engaged in academic dishonesty, the

            faculty member will call the student into a private meeting in the faculty member’s office.

            (The division chair will be notified of and will approve any action.)

Step 2. The faculty member will confront the student with the evidence of dishonesty and/or 

            academic irregularity. The faculty member and the student will discuss the specifics of

            what occurred. If the student confesses and accepts responsibility for academic

            dishonesty, then the faculty member will ask the student to sign in his/her own

            handwriting, a statement which makes clear that the student admits responsibility for the

            academic dishonesty. The faculty member will then consult with the division chair. The

            faculty member is then free to reprimand the student, to give a failing grade for the

            assignment, or to require the student to resubmit the assignment in question. With

            approval of the division chair, the faculty member can increase the penalty up to and

            including a “WF” for the course if the incident(s) merit this severe penalty.

Step 3. If the student refuses to sign a statement accepting responsibility for the act(s) of

            academic dishonesty, then a full hearing on the matter must be held. The faculty member

            and chair will document this incident and schedule a meeting with the student. This

            information will be turned over to the Academic Dean, who will make the determination 

            of charges against the student and notify him/her in writing. The charges will be mailed by

            the Academic Dean to the student along with a notice to appear at a hearing, and, if the

            student wishes, to bring witnesses. At least three days’ notice is necessary unless the

            student waives the notice in writing.

Step 4. If the student requests a hearing, the Academic Dean has the option of hearing the case for

            administrative adjudication, convening a special hearing panel including faculty and

            students, or of referring it to the Student Life Hearing panel which handles all other

            disciplinary matters on campus. The committee will provide its recommendation to the

            Academic Dean. The Student Life Hearing Panel, when hearing cases of academic

            dishonesty, will include two faculty members, two students (one of whom will be the

            SGA president and the other an associate justice,) and the Director of Student Life, who

            oversees campus discipline and the Code of Conduct. The Chief Justice of the SGA chairs

            the panel. The Vice President for Student Affairs will serve as advisor to the panel for all

            academic dishonesty cases. In general, the decision of the Academic Dean or his/her

            designee will not be appealed to the Student Life Hearing Panel. An appeal of the Dean’s

            decision will go directly to the President who may choose to use the Student Life Hearing

            Panel to make a recommendation to him.

Step 5. The student has a right to appeal the decision of the hearing officer or hearing panel

             within ten calendar days of the decision. The appeal will be to the President or his

             designee. The President’s decision is final. The President reserves the right to review all

             disciplinary cases and the judgments made during the process.

 

http://www.abac.edu/catalog/2007_2008/AcademicPolicy.pdf

 

 

 

If there is a student in this class who has specific needs because of learning disabilities or any other disability, please feel free to contact the instructor.

 

 

This is a partial syllabus. More detailed information relating to the class and Instructor will be made available to each student.

 

 

 

COURSE DESCRIPTION, PRE/CO-REQUISITES, TOPICS, AND GOALS:

Chemistry 2041 (3 credit hours) has three 50 minute lectures per week and is accompanied by one three-hour laboratory ( CHEM 2041L, 1 credit hour) per week. It is the second of a two-semester sequence in organic chemistry.  The course appears in Area F in your course curriculum. This course is designed for students who are enrolled in transfer programs in majors such as Chemistry, Biochemistry, Biology, … and in pre-professional programs, such as Pharmacy, Medicine, Veterinary Medicine, Dentistry, etc. In this course, emphasis will be placed on the structure, reactions, and properties of alcohols, aldehydes and ketones, carboxylic acids and their derivatives, phenols, amines and their derivatives.

IR, MS, and NMR spectroscopies will be utilized in determining the structure of organic compounds. 

 

The pre-requisite for CHEM 2041 is passing CHEM 2040 and CHEM 2040L with a grade of C or better. You must show proof that you fulfill the condition to be in this class. In order to do that, turn in a printout of your transcript highlighting the part that shows that you have passed CHEM 2040 and CHEM 2040L. This must be done by the next time the class meets. Any student taking CHEM 2041 must also be registered in the corresponding lab: CHEM 2041L. Departure from this rule must be allowed by the appropriate authority of the school.

 

Chem 2041 seeks to reach a variety of objectives. An obvious goal is to obtain a basic knowledge of those chemistry topics just mentioned.

 

More specific objectives include mastery of nomenclature rules, spectroscopic structural identification methods, properties and chemical reactions (including mechanisms) leading to and involving the organic compounds covered.

 

However, the goals for Chemistry 2041 go far beyond an understanding of the chemistry of organic compounds. Your instructor and all other people and organizations involved in your education hope that you will realize that chemistry is not just a subject that is to be studied, but is rather a subject that may be used to explain, interpret, and predict much of what goes on around you. We hope that students learn to see chemistry as a subject of fundamental importance to your everyday life.

 

Another goal is to master the problem solving strategies used by chemists to the point that the student realizes that it is useful to non-chemistry related subjects and endeavors. Additional goals include the realization that chemistry is an ever changing body of knowledge.

 

As a final goal, we hope that you will learn to continually ask questions as an aid in your pursuit of knowledge, and that you will use the gained knowledge to bec0ome a better person, better for yourself and your community.

 

REQUIRED MATERIALS

  • Textbook: Organic Chemistry, 6h edition (2005). Author: L. G. Wade, Jr. Publisher: Prentice Hall.
  • Online Homework Material: accessible using an Access Code purchased from the bookstore. Two websites will be used:    * Course Compass which carries quiz material;

* ACE (Achieving Chemistry Excellence), which enables students to draw the structures of molecules.

Both websites are accessed using the same login name and password.

 

Additional material:

  • Solutions Manual for “Organic Chemistry” by L. G. Wade, Jr. Author: J. W. Simek. Publisher: Prentice Hall.
  • Molecular Model kit.
  • ISIS DRAW molecular structure drawing program. If you have not done so already, you will need to download and install the program on your computer. The instructions to do that can be found on the following website: http://www.abac.edu/oits/training/Math/isis_draw.htm
  • Scientific Calculator

 

 

EXPECTED COURSE ACTIVITIES

Quizzes & Homework will be regularly given on topics covered in class. In-class quizzes will be given during the first ten minutes of the lecture. Alternatively, a number of quizzes will be given online, both on Course Compass and ACE. Quizzes are designed to assess the extent to which students understand the concepts covered in class. Furthermore, this is true especially for online quizzes, they impel each student to get fully engaged in all the operations conducted in class, which is a crucial step in the acquisition of knowledge and skills. Quiz questions will be a combination of multiple choice and essay types. Instead of a mere statement of facts, a typical multiple choice question will be a statement of fact and its justification. This not only better demonstrates knowledge of the material, but it also limits to a minimum the probability of obtaining a high grade through picking the correct answer by mere luck.

 

Even though they take a considerable amount of time to grade, essay questions provide better insight into student knowledge and thinking process, which allows for better intervention to improve student knowledge quality and level when such intervention is warranted. Rather than rote memorization, the correct answers to the questions will combine knowledge and explanation of concepts, and /or ability to rationalize phenomena and procedures, which are better tools to assess mastery of concepts and problem solving procedures.  

 

Homework will be assigned using mostly internet resources, more specifically Course Compass and ACE. Due dates will be announced at assignment times. Homework activities will help the students develop problem-solving skills. Quiz and homework grades will add up to a total equal to one unit test.

 

In order to insure that the learning objectives are individually reached in each chapter and to allow students to connect what they study in class to various aspects of their daily lives, personalized chapter assignments will be given at the beginning of each chapter and will be turned in at the end of the chapter. The chapter assignments are designed to incite students to get personally involved in the learning process while solving problems. Grades of chapter assignments will be incorporated into test grades.

 

Group homework may also be assigned in the form of projects. The projects will deal with selected topics covered in class. The goal of the projects is to give the students the opportunity to solve problems in teams and apply the concepts covered in class to outside-class situations. Grades of projects will be incorporated into test grades

 

No make-ups will be allowed after a corrected quiz/homework has been returned to the students.

 

TESTS

Lecture tests will include four unit tests and one final test.  The material for each unit test will be announced in due time. The goal of each test will be to assess the ability of students to demonstrate concept understanding, critical thinking and problem-solving. Test questions will be a combination of multiple choice and essay types.

 

Instead of a mere statement of facts, a typical multiple choice question will be a statement of fact and its justification. This not only better demonstrates knowledge of the material, but it also limits to a minimum the probability of obtaining a high grade through picking the correct answer by mere luck.

 

Even though they take a considerable amount of time to grade, essay questions provide better insight into student knowledge and thinking process, which allows for better intervention to improve student knowledge quality and level when such intervention is warranted. Rather than rote memorization, the correct answers to the questions will combine knowledge and explanation of concepts, and /or ability to rationalize phenomena and procedures, which are better tools to assess mastery of concepts and problem solving procedures. 

 

Each unit test (except for the first one) will carry a number of questions from previous test(s), to insure permanent contact with the most important aspects of the material covered previously and to provide better preparation for the final test.

 

A compelling and verifiable reason will be required for make-up tests and only one make-up test will be allowed per student. The make-up test will be done at the time of the final examination, only if it was pre-approved at the time the corresponding regular test was missed.

The final test will cover all the material of the semester. No make-ups will be allowed for the final test.

 

EVALUATION

The course grade will be based upon student performance detailed as follows:

1. Four unit tests

2. One final test = one unit test

3. Quizzes and homework = one unit test

Overall: 6 performance items, each carrying 16% of the total lab grade.

4. Attendance and Conduct: 4% of total lab grade

Total %: 100%

 

Percentage/grade conversion

Percentage       Grade

90-100 %         A

80-89               B

70-79               C

60-69               D

0-59                 F

 

LOWEST TEST GRADES

In order to insure better grade and competency correlation, the lowest test grade will be dropped at the discretion of the instructor, if the conduct of the students warrants it and if that would result in a better letter grade. The test to be dropped must have been actually taken. Skipped tests do not apply.

 

ACCOMMODATIONS FOR STUDENTS WITH LEARNING DISABILITIES

Special accommodations will be provided for students with learning disabilities on a case-by-case basis. Any student who fulfills learning disabilities conditions must get in touch with the teacher in order to insure his/her case will be dealt with properly and in a timely manner.

 

HOW TO SUCCEED IN ORGANIC CHEMISTRY II

·                     Attend all classes

·                     Pay attention in class

·                     Participate in classroom activities

·                     Participate in group quiz activities

·                     Ask questions to clarify unclear material.

·                     Review the material covered in class:

            *          The very day it is covered

            *          Two or more times before quizzes and tests.

·         Work out the examples

            *          given in class

            *          that are similar to the examples solved in class

·         Do and turn in all assignments

·         Take all quizzes and tests

·         Display appropriate behavior in class.

·         Follow the rules on work ethics.

 

 It may be possible to memorize material by “cramming” a day or two before an exam, but the benefits of this method of studying are uncertain at best. However, progressive review and practice, by working gradually on the material as it is covered, leads to understanding, remembering, and being able to interpret and apply it are far superior and more productive study methods. Working in small groups has been proven an excellent way to study. If you can explain some concept or problem to another student, you are certainly well on your way to understanding it yourself. It also helps to see questions other students have, as you may at some point have those same questions yourself.

 

Some other tips to help you succeed include:

           study 2 to 3 hours outside of class for each hour in class

           pay close attention to diagrams, models, analogies, and charts and determine their significance, implications, and connections to the concepts under study.

·               try to understand the physical basis of mathematical formulae

           work problems in a test-like mode (this means with no notes, no text, and in a limited amount of time)

           use all the help resources available to you, including instructor office hours, other students, and the academic assistance center

           get a good night’s sleep before exams

·                     Analyze the questions you missed in a quiz or test and identify the activity you need to conduct and the habits and skills you need to acquire in order to perform better next time.

           make up and answer alternative questions for every question asked in lectures, quizzes, homework, and review sessions. This helps reinforce your knowledge and test taking skills.

 

CLASSROOM CONDUCT AND ACADEMIC ETHICS

In order to enhance successful learning, lectures must take place free from distraction. As a result:

·         Food and drink are strictly prohibited in class.

·         You are allowed to talk in class only as instructed by the teacher or when asking questions to the teacher.

·         Cellular phones are allowed in class, but they must be turned off during lecture time. Instances of class disruption by cell phone call will result in additional assignments due the next time the class meets.

·         2% of the lecture grade will be reserved for classroom conduct. Following the 1st two warnings, five classroom conduct citations (by the teacher) will result in forfeiture of the classroom conduct grade.

Cheating, plagiarism or any other form of dishonesty is strictly prohibited.  Sanctions will be imposed on anybody caught in the act. Depending on the gravity and / or frequency of misconduct, the punishment could amount to failure in and dismissal from the class. More information on this and other policies can be found a this link: http://www.abac.edu/catalog/2007_2008/AcademicPolicy.pdf

 

CAP/HAT/ELECTRONIC DEVICES POLICY

No caps/hats will be allowed on examination days and when/if quizzes are given. Furthermore, the use of any device which can deliver and/or receive electronic messages will be strictly prohibited. The source and the destination of the messages will be sanctioned equally.

 

Withdrawal from the course

If a student needs to withdraw from this course, the course should be dropped before the deadline date of February 28, 2008. Dropping out of the class leads to dropping out of the lab and vice-versa. If the course is dropped by the deadline date, the student will be awarded a grade of W. After the withdrawal date, the course can be dropped with a grade of “W” only under very extenuating circumstances. In this case, the withdrawal must be approved by the instructor and the Division Chairman (Dr. Ray Barber of the Science-Mathematics Division). Otherwise, a grade of “WF” will be awarded. A student who stops attending class without officially withdrawing from the course is subject to this attendance policy and will receive a grade of “F” for the course. 

 

It is important to notice that even when it is done by the deadline, dropping classes may have negative effects on such processes as Hope scholarship (which considers attempted instead of completed hours) or insurance (some companies require full time status for coverage).

 

 

CHEM 2041 ORGANIC CHEMISTRY II

LEARNING OUTCOMES

As we cover the chapters scheduled for this course, you will be empowered to achieve the following learning outcomes:

  1. Describe and explain the basic principles, and apply the techniques of mass spectrometry (MS), infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy to identify the structure or structural characteristics of organic compounds.
  2. Identify the reactants and products, and describe and explain the mechanism and the influential factors of addition reactions on carbon-carbon double bonds
  3. Identify the reactants and products, and describe and explain the mechanism and the influential factors of addition reactions on aromatic compounds.
  4. Determine the names using structures and structures using names, and describe and explain the properties, preparation methods and reactions of aldehydes and ketones.
  5. Determine the names using structures and structures using names, and describe and explain the properties, preparation methods and reactions of amines.
  6. Determine the names using structures and structures using names, and describe and explain the properties, preparation methods and reactions of carboxylic acids and their derivatives.
  7. Identify the reactants and products, and describe and explain the mechanism and the influential factors of alpha substitution and condensation and conjugate addition reactions of enols and enolates

 


Tentative instructional Schedule

Textbook: Organic Chemistry, 6th edition (2006). Author: L. G. Wade, Jr. Publisher: Prentice Hall.

 

Week               Objective         Contents to be covered                                   Textbook Page

 

I & II               1                      Mass Spectrometry &                                     508

                                                Infrared Spectroscopy                                   

 

III                    1                      Nuclear Magnetic Resonance                         559

 

                                                Test I  

 

III & IV          2                      Addition reactions on carbon-carbon

double bonds                                                  252

 

V                     3                      Aromatic Electrophilic Substitution Reactions           749

 

                                                Test II

 

VI & VII         4                      Aldehydes and Ketones                                 805, 818

 

VIII                 4                      Nucleophilic addition reactions on

carbonyl groups                                               829

 

                                                Test III

 

IX - XII          5                      Amines                                                                        870

 

XIII & XIV    6                      Carboxylic Acids and Derivatives                  935, 978

 

XV                  7                      Alpha Substitution, Condensation and

Conjugate additions of Enols and Enolates   1041

                       

                                    Test IV

 

XVI                                         Final Test